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White to light gray crystal or crystalline powder, with special odor, melting point 126.5~128.5℃, boiling point 300℃, slightly soluble in water (25℃, <1%), easily soluble in ethanol (120%), acetone (190%), ethyl acetate (100%), insoluble in toluene, and soluble in animal and vegetable oils. MTBHQ is mainly used as polymer inhibitor, heat and light stabilizer and industrial antioxidant.
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White or off-white crystalline powder; moderate smell, non-toxic; most important issue content ≥98.5%; relative density 1.09; melting point 212-218℃; solubility (g/100g solvent, 25℃): ethanol 35.1, acetone 39.0, ethyl acetate forty eight.eight, benzene 1.5, insoluble in fuel, insoluble in water; colorless, non-polluting, smooth to disperse, and so forth. Characteristicsf DTBHQ:Chemical call: 2,five-di-tert-butylhydroquinone (2,5-di-tert-butylhydroquinone)Abbreviation: DTBHQEnglish name: 2,five-di-tert-butylhydroquinone (DTBHQ)Molecular formula: C14H22O2Molecular weight: 222.33Type
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At high temperatures, a series of complex chemical reactions such as oxidation, decomposition, polymerization, and hydrolysis are prone to occur, resulting in a rapid increase in the acid value, peroxide value, and carbon base value of roasted foods. In the later stage of storage and sales, unpleasant odors are easily produced. The use of TBHQ can effectively delay oil oxidation in pastry foods.Baked pastry foods require a higher temperature during the baking process, such as cakes and bread, which require a baking temperature of 160C~190C.
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It is a white to light gray crystalline or crystalline powder with a very slight special odor. It is soluble in ethanol, acetic acid, ethyl ester, isopropanol, ether, and oils, and is almost insoluble in water (25 ℃,<1%; 95 ℃, 5%). TBHQ is an oil soluble antioxidant that can prevent or delay the oxidation and deterioration of fats in food.
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Product DescriptionIn addition, TBHQ also has characteristics such as high temperature resistance, oil solubility, and antibacterial properties, which are widely used in edible oils, fried foods, etc. By comparing the effects of various antioxidants in different products, summarizing the usage patterns, and providing theoretical basis for the application of TBHQ.The oil in oily food undergoes oxidation in the air, producing free radicals and peroxides, which are early indicators of food rancidity.
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This product does not affect the color and flavor of food, and is not used for coloring iron containing foods.It can effectively delay oil oxidation, improve food stability, and significantly extend the shelf life of oil and fat rich foods.TBHQ can be used for edible oils, fried foods, dried fish products, biscuits, instant noodles, instant boiled rice, canned dried fruits, pickled meat products, roasted and fried nut foods (supplemented in February 2007), etc.The pumping method injects the TBHQ concentrated solution prepared by the seed method into a pipeline with a fixed flow rate and flow r
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TBHQ can be used for edible oils, fried foods, dried fish products, biscuits, instant noodles, instant boiled rice, canned dried fruits, pickled meat products.This product does not affect the color and flavor of food, and is not used for coloring iron containing foods.The antioxidant effect of this product is very ideal, 5-7 times stronger than BHA, BHT, and PG.
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1.Product CharacteristicsTertiary butylhydroquinone(TBHQ), white or slightly reddish brown crystalline powder, has a very light special fragrance, almost insoluble in water (about 5 per cent), soluble in ethanol, ethyl acetate, ether and other organic solvents.Tertiary butylhydroquinone has synergistic properties and can be used synergistically with other antioxidants (e.g. BHA, B HT) as well as chelating agents (e.g.
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2-tert-butylhydroquinone is white to light grey crystalline or crystalline powder, with very slight special smell, soluble in ethanol, acetic acid, ethyl alcohol, isopropyl alcohol, ethyl alcohol and oil, etc., a few are insoluble in water (25 ℃ <1%: 95 ℃ <5%) TBHQ is a kind of oil-soluble antioxidant, which can prevent or prolong the oxidation of the fat and oil deterioration in food.2.Product Characteristics2-Tert-butylhydroquinone is a highly efficient, low-toxic antioxidant phenolic antioxidant with excellent antioxidant effect, and the existing food antioxidants BHA, BHT, PG, etc.
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The use of TBHQ can effectively delay oil oxidation in pastry foods,appropriate selection of antioxidants can inhibit the rancidity of oily food production and prolong the storage life of the product. Shelf life is considered an effective way to prevent the product from deteriorating due to oxidation.
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1.Product ParametersTert-butylhydroquinone (TBHQ), also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective. Tertiary butylhydroquinone (t butylhydroquinone), referred to as TBHQ molecular formula for CH1402, molecular weight of 166.22.2.Academic research and developmentLtd.
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Eastman in the United States, Camlin in India, and others. At present, the production of tert butyl hydroquinone both domestically and internationally adopts the tert butylation method of hydroquinone, as shown in Figure 2. According to different classifications of alkylation reagents, it can be divided into tert butyl method, isobutylene method, and MTBE method.
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In the United States and China, the maximum allowable dosage of TBHQ in food is 200ppm,At present, the production of tert butyl hydroquinone both domestically and internationally adopts the tert butylation method of hydroquinone, as shown in Figure 2. According to different classifications of alkylation reagents.Both domestic and foreign patent literature have reported this process, such as using toluene or xylene as solvents, the selectivity and yield of this reaction are relatively ideal.
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Tert butyl hydroquinone (TBHQ), also known as tert butyl hydroquinone, is a white crystalline powder with a melting point of 126.5-128.5 ℃ and a boiling point of 300 ℃. Its CAS number is 1948-33-0, and it is easily soluble in ethanol and ether. It is the most effective antioxidant for most oils, especially vegetable oils. T-butylhydroquinone, abbreviated as TBHQ, has a molecular formula of Cl0H1402 and a molecular weight of 166.22. [1] It is a white to light gray crystalline or crystalline powder with a very slight special odor.
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Physical and chemical properties:Density: 1.328g/cm3Melting point: 172-175℃Boiling point: 286℃Flash point: 141.6Refractive index: 1.612Critical temperature: 549.9℃Critical pressure: 7.45MPaIgnition temperature: 516℃Explosion limit (V/V): 15.3%Lower explosion limit (V/V): 1.6 %Property: white needle crystal, discolored by light, with special odorSolubility: soluble in hot water, soluble in cold water, ethanol and ether, slightly soluble in benzene Packaging, storage, transportation:1: 25KG (net weight) kraft paper laminated bag, lined with double polyethylene plastic bag.2: Store in a cool
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The US Food and Drug Administration (FDA) allows TBHQ to be used alone or in combination (with BHA or BHT) for oil or fatty foods, including volatile essential oils, with a maximum allowable dosage of 200PPM. It can also be used in non-alcoholic beverages, margarine, and mixed nuts.TBHQ, also known as tert butyl hydroquinone, is a phenolic oil soluble antioxidant. TBHQ has high efficiency and stability, which can extend the shelf life of foods rich in oil and improve food safety.
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Possible reaction pathways of 2,5-di-tert-butyl-hydroquinone (2,5-DTBHQ).Valgimigli et al. proposed a mechanism wherein semiquinone (2) reacts with molecular oxygen to produce 2,5-di-tert-butyl-1,4-benzoquinone (2,5-DTBBQ) and hydroperoxyl radical (HOO∙). The semiquinone (2) terminates a second propagation chain via either hydrogen abstraction (Reaction II) or addition reaction (Reaction IV) and these reaction pathways play a very critical role in the inhibition process.
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Introduction of nature:TBHQ is sort of insoluble in water (approximately five‰), soluble in ethanol, acetic acid, ethanol, isopropyl alcohol, ether and vegetable oil, lard, and so forth. Nearly insoluble in water (25℃, <1%). Boiling factor 295℃, melting factor 126 -128.5℃. It has the effect of stopping the failure of most fats and oils, specially vegetable oils. It does no longer trade color in touch with iron and copper, but can turn red if alkali is present.
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Pastry and bread stored in the air for a long time are prone to spoilage due to oxidation of their lipid components. The oxidation of oil components not only causes food discoloration, discoloration, destruction of vitamin A, D, E, and other components, but also produces odor.
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White or off-white crystalline powder; slight odor, non-toxic; main component content ≥98.5%; relative density 1.09; melting point 212-218℃; solubility (g/100g solvent, 25℃): ethanol 35.1, acetone 39.0, ethyl acetate 48.8, benzene 1.5, insoluble in gasoline, insoluble in water; colorless, non-polluting, easy to disperse, etc. Characteristicsf DTBHQ:Chemical name: 2,5-Di-tert-butylhydroquinone (2,5-di-tert-butylhydroquinone), abbreviation: DTBHQEnglish name: 2,5-Di-tert-butylhydroquinone (DTBHQ)Molecular formula: C14H22O2Molecular weight: 222.33Classification belongs to: Polyphenols CAS: 8
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TBHQ has good oil solubility and thermal stability, and does not change in color after heating.They are only suitable for high water content oil and fat foods such as biscuits, instant noodles, artificial milk oil, and mayonnaise. When the oil contains a large amount of metal ions and oxygen, the addition of antioxidants can inhibit the formation of peroxides.Oxidized fish oil is harmful to human health, so it is important to prevent oxidation and improve the stability of fish oil.
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It is soluble in ethanol, acetic acid, ethyl ester, isopropanol, ether, and oils, and is almost insoluble in water (25 ℃,<1%; 95 ℃, 5%). TBHQ is an oil soluble antioxidant that can prevent or delay the oxidation and deterioration of fats in food. As a food additive, TBHQ has been used in more than 20 countries such as the United States. In 1992, China was approved for use in oil and fat containing foods, dried fish products, biscuits, instant noodles, canned oil containing foods, pickled meat products, etc.
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Vegetable oil, animal fat, chewing gum, soup, seasoning, vitamins, grain food, nuts, essence, sausage, animal feed, grain food packaging, candy, instant potatoes, flavor substances, yeast, cosmetics, etcAs an antioxidant, it must meet the following requirements as much as possible: no harm to the human body; There should be no bad taste, smell, or color; Low concentration can be applied; If added to oil, it is fat soluble and can still maintain effective antioxidant capacity after processing; Need to be fast, effective, and cost-effectiveAntioxidants are substances that prevent or delay food o
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At present, the most commonly used antioxidants for oils and their products are BHA, BHT, PG, TBHQ, and tocopherols. As for vegetable oils, their antioxidant capacity is in the order of TBHQ>PG>BHT>BHA. As for animal fats, the order of their antioxidant capacity is TBHQ>PG>BHA>BHT. For anhydrous milk fat, their antioxidant capacity is in the order of PG>TBHQ>BHA>tocopherols.
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